n-tetracosane
- n-tetracosane的基本解释
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[化] 正二十四烷, 正二十四碳烷
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CA-CTSs including N,O-carboxymethyl chitosan,N,O-1-carboxyethyl chitosan (N,O-1-CEC),N,O-2-carboxyethyl chltosan(N,O-2-CEC),N-carboxymethyl chitosan and N-1-carboxyethyl chitosan(N-1-CEC) are quaternized using active quaternary salts prepared in laboratory.5 series including 25 kinds amphoteric chitosans characterized with polymeric ampholyte,in which 24 kinds are synthesized firstly,are obtained, 2-Hydroxypropyl dimethylbenzyl ammonium N,O-(1-carboxyethyl) chitosan chloride (GDMBA-N,O-1-CEC) is hydrolyzed into serial low molecular weight GDMBA-N, O-1-CEC with acid as catalyst and microwave as assistant instrumentality innovately.
以合成的活性季铵盐改性了N,O-羧甲基壳聚糖、N,O-1-羧乙基壳聚糖(N,O-1-CEC)、N,O-2-羧乙基壳聚糖(N,O-2-CEC)、N-羧甲基壳聚糖和N-1-羧乙基壳聚糖(N-1-CEC)等羧烷基壳聚糖,得到5个系列25种具有两性高分子电解质特征的新季铵化羧烷基壳聚糖,其中24种为首次合成;创新提出以微波辅助酸催化的方法催化2-羟丙基二甲基苄基-N,O-(1-羧乙基)壳聚糖氯化铵(GDMBA-N,O-1-CEC)水解,得到了低分子量的GDMBA-N,O-1-CEC。
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This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.
本文介绍了醛的不对称烯丙基化反应,以光学纯酒石酸为原料,研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性,全文共分三部分十个章节:第一部分对当前手性药物和手性技术进行了概述,并由此展开了本文的研究背景和任务;第二部分为有机合成部分,对醛的不对称烯丙基化反应进行了深入探讨,以苯甲醛为原料对反应条件进行优化,在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选,优化配体回收实验条件,最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性,结晶回收的手性配体光学纯度保持不变。
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Three cationic surfactants, N -dodecyl- N -(2-hydroxyethyl)- N , N -dimethylammonium bromide, N -tetradecyl- N -(2-hydroxyethyl)- N , N -dimethylammonium bromide and N -cetyl- N -(2-hydroxyethyl)- N , N - dimethylammonium bromide have been synthesized.
合成了 N -十二烷基- N -(2-羟乙基)- N , N -二甲基溴化铵、 N -十四烷基- N -(2-羟乙基)- N , N -二甲基溴化铵和 N -十六烷基- N -(2-羟乙基)- N , N -二甲基溴化铵等3个季铵盐阳离子表面活性剂。
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n th member:第n项
n sphere bundle n球丛 | n th member 第n项 | n th partial quotient 第n偏商
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n th partial quotient:第n偏商
n th member 第n项 | n th partial quotient 第n偏商 | n th power operation n次幂运算
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n th partial quotient:分 的)第 n 个部分商
n-th order matrix n 阶方阵 | n-th partial quotient ( 分 的)第 n 个部分商 | n-th partial sum 第 n 部分和