英语人>词典>英汉 : ketenes的中文,翻译,解释,例句,拼写相似词汇
ketenes的中文,翻译,解释,例句,拼写相似词汇

ketenes

单词解释请参考:ketene
ketenes的基本解释
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烯酮类

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Ketenes, notably dimethyl ketene, readily undergo oligomerization and polymerization

烯酮,特别是二甲基烯酮,很容易齐聚和聚合。

Because of their strong nucleophility of NHCs, the asymmetric Staudinger reaction between ketenes and imines catalyzed by chiral NHC was achieved, gave -lactams with excellent enantioselectivities.

中文摘要我们组利用氮杂环卡宾的亲核性,成功地实现了氮杂环卡宾催化的烯酮与亚胺的Staudinger反应。

In the second part of this thesis, a formal [2+2] cycloaddition ketenes and dialkyl azodicarboxylates was studied. We found that by adjusting the substituents in the diazenes, the reaction mode can be completely switched, and furnish four-membered-ring products, aza-b-lactams, the enantioselectivity was up to 91%.

经研究发现,通过对偶氮化合物取代基团的改变,我们可以实现[4+2]环加成反应到[2+2]环加成反应的转变,在手性氮杂环卡宾的作用下,对具有各种取代基的烯酮都可以很好的产率得到氮杂b-内酰胺,其对映选择性最高可以达到91%。

As open-chain hydroxy aldehydes and hydroxyl ketenes, the monosaccharides are very reactive.

以开链的羟基醛和羟基酮形式存在的单糖非常活泼。

In the first part of this thesis, a formal [4+2] cycloaddition of ketenes with N-benzoyldiazenes catalyzed by chiral NHCs was studied, which gave 1,3,4-oxadiazin-6-ones in very high yields and enantioselectivites.

论文的第一部分内容是在手性氮杂环卡宾的催化下,烯酮与N-苯甲酰偶氮化合物的环加成反应,合成各种手性的噁二嗪酮,它们还可以经过简单的两步一锅法制备手性氨基酯。

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