intramolecular [,intrəmə'lekjulə]

intramolecular的基本解释

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[医] 分子内的

与intramolecular相关的网络例句 [注：此内容来源于网络，仅供参考]

For intramolecular electron transfer reactions in solution,the fluctuations of the intramolecular vibrational modes are much faster than that of solvent mode.Thus,the reaction-diffusion equation is commonly used to describe the motion of solvent,with a sink function to treat the vibrational high-frequency mode.Based on this theory-so -called the Sumi-Marcus theory,we proposed an imaginary-time split operator approach to solve the reaction-diffusion equation.The approach is applied to evaluate the intermolecular ET rate between oxazine 1 and N,N-dimethlaniline.By measuring the two average survival times of the donor state probability and the rate constant in long time limit,the full kinetics of the ET is revealed with a variety of sink functions.

对于扩散控制的溶液中的电子转移反应，分子内振动模的运动比溶剂运动快很多，Sumi-Marcus理论提出用反应扩散方程(reaction-diffusion equation)处理溶剂的扩散运动，而分子内的振动用sink函数来表示，我们基于此理论发展了用虚时间分裂算符的方法(imaginary-time Split operator approach)解反应扩散方程，并将其应用于嗪1(oxazine 1，OX1)和N，N-二甲基苯胺分子之间的电子转移反应，Sink函数采用几种不同的微扰表达式，通过计算得到给体几率衰减的两种平均速率和长时间极限下的速率常数，揭示了该体系电子转移过程中的一些动力学性质。

It was found that the geometries of the studied materials were significantly affected by the ring size and intramolecular charge transfer. The HOMO level, LUMO level, and band gap of the studied model compounds were well controlled by the acceptor strength. However, the electronic properties of the studied polymer showed a significant different trend with the acceptor strength due to the geometrical transformation. The model compound of EDOT-TP and T-TP has the aromatic geometry but is transformed to the quinoid geometry for large intramolecular charge transfer. The small bond length alternation and large acceptor strength in the EDOT-BDP polymer also results in the smallest Eg of 0.7 eV among the studied polymers.

我们发现环的大小以及分子内电荷转移对结构有很大的影响，而小分子的HOMO、LUMO和能隙受到电子受体强度所控制，然而，高分子的电子特性与其构成分子却有明显不同的趋势，这主要是由於分子结构的转变，如小分子EDOT-TP以及T-TP因分子内电荷转移，使其高分子结构由aromatic转变成quinoid；而EDOT-BPP因其键长改变量小和良好的电子受体强度，使其能隙仅0.7个电子伏特。

During the investigation of the reactivity of O_SCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2 and O_SCl_2(PPh_3)_2CH=C(PPh_3C(=CH_2)CH=CH2, several stable osmacycles with novel structure, such as osmabenzenes, osmafurans, osmacycles containing intramolecular-coordinated allene, intramolecular-coordination osmacycles containing osmacarbene, an osmacyclopentadiene, were isolated during the investigation of the reactivity of O_SCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2 and O_SCl_2(PPh_3)_2-CH=C(PPh_3C(=CH_2)CH=CH_2.In addition, some convenient and efficient methods to prepare these osmacycles were developed.

首先，合成出两种具有反应活性的金属杂五元环IC配合物OsCl_2(PPh_3)_2CH=C(PPh_3CHCH=CH_2和OsCl_2(PPh_3)_2CH=C(PPh_3C(=CH_2)-CH=CH_2，并对它们进行了系统表征；进而，研究了这些活性五元配合物的反应性，合成出多种稳定的锇杂环配合物，其中包括锇苯、锇呋喃、含配位联烯的锇杂IC环化合化物、含锇卡宾的IC环化物、首例锇杂环戊二烯化合物等多元化的产物。

与intramolecular相关的网络解释 [注：此内容来源于网络，仅供参考]

intramolecular：分子内的

intracavitary irradiation 腔内照射 | intramolecular 分子内的 | intranuclear 核内的

intramolecular：分子内部的

intramolecular rearrangement 分子重排 | intramolecular 分子内部的 | intramontane basin 山间盆地

intramolecular：分子內的 分子内的

intralaminal complexing 腔內複合 腔内络合 | intramolecular 分子內的 分子内的 | intrathecal injection 鞘內腔給藥 鞘内注射

intramolecular：分子内的=>分子内

intramode 模内 | intramolecular 分子内的=>分子内の | intramolecular arylation 分子内的芳基化,分子内芳基化

intramolecular force：分子内力

roller cutter (锥形)滚刀(隧道掘进机用) | intramolecular force 分子内力 | globar resistance heater 碳(化)硅棒电阻式发热元件