hazel alder
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TREES ALDER The Alder is the tree of fire.
赤杨: 赤杨是火的树木。
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The Diels-Alder cycloadditions of [60] fullerene for preparation of optical limitingmaterials are discussed in chapter 3 and 6. Soluble cycloaddition derivatives of 〓aresynthesized by the reaction of 〓 with indene,1,1'-biindene andcyclopentadiene derivatives.〓Particular, the Diels-Alder cycloaddition of 〓 with1,1'-biindene under controlled conditions affords the stable monoadduct 〓〓of novel structure, which was confirmed by HPLC, FTIR, FD-MS,〓NMR,〓 NMR, HMQC and HMBC spectra, Its two bridgehead cage carbons resonate at70.91ppm, The 〓 NMR spectra showed 38 lines consistent with the 〓 symmetryassociated with [6,6] addition. The 〓 shows similar optical limitingproperties to that of 〓 in toluene for 8ns laser at wave length 532nm. Moreover, thehigh solubility of this adduct in polar solvents such as THF, acetone enables itsincorporation into sol-gel glass matrix. The thin films prepared via the sol-gel methodshow improved OL behaviour compared to those of 〓. The langmuir-Blodgett filmformation and uv-visible absorption of 〓 are also investigated. LBmonolayer of this compound is prepared on the air-water interface at 〓 mol/l. In chapter 4, three water-soluble derivatives of [60] fullerene: fullerol(1), theaddition product (2)of fullerol (1)with polyvinylpyrrolidone and fumaric acidderivative of 〓(3) are synthesized and characterized.
通过Diels-Alder环加成反应,用茚〓和1,1'-联茚〓及取代茂合成了一系列可溶性的〓环加成衍生物,发现可控制反应条件,使1,1'-联茚与〓反应,并高产率地得到具有新颖结构的单加成物,用HPLC、FTIR、FD-MS 及〓、HMQC、HMBC等多种波谱技术对其结构进行表征,测得它的两个〓杂化的桥头碳的化学位移为〓ppm,证明生成的衍生物为6∶6闭式环加成,〓NMR谱中共给出38个信号,表明〓联茚衍生物分子具有〓对称性;在波长532nm,脉冲宽度8ns的激光下,〓联茚衍生物的甲苯溶液的光限幅性能与〓的甲苯溶液相近,由于〓联茚单加成衍生物熱稳定性好,在四氢呋喃,丙酮等极性溶剂中溶解性好,能分别均匀地掺入溶胶-凝胶中,已发现它的溶胶(so1)光限幅性能优于纯〓的光限幅性能;使用Langmuir-Blodgett技术将〓联茚衍生物在空气和水的界面进行了LB单层膜和多层膜实验以及UV-Vis吸收谱研究,通过等温压缩曲线测试,证明浓度为〓〓时,〓联茚衍生物能够形成单层膜。
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One synthetic strategy started fromγ-butyrolactone 38, from which a cyclohexadiene intermediate 30 was prepared in an overall yield of 44% in a 7-step procedure after y-butyrolactone underwent a-bromination, dehydrobromination, Diels-Alder reaction, aminolysis, benzylation, bromination and dehydrobromination, with the key step being the Diels-Alder reaction under harsh condition.
其中一个路线从γ-丁内酯38开始,连续经过α-溴化、脱溴化氢、Diels-Alder反应、胺解、苄基化、溴化和脱溴化氢共7步反应,制备了一个环己二烯衍生物30,总产率44%,关键步骤是高温高压下Diels-Alder反应。
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tree hazel;Mediterranean hazel:土耳其榛
本色榛 European hazel;hazeltree;common hazel | 土耳其榛 tree hazel;Mediterranean hazel | 贝氏棒花木 tsanya
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black alder:黑桤木
矮桤木 Alnus fruticosa Rupt. | 黑桤木 Alnus glutinosa Gaertn.;alder-tree;black alder;common alder | 辽东桤木 Alnus hirsuta var.sibirica Schneid;A.sibirica Fisch.;A.tinctoria Komar.
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alder grove:赤杨林
alder 赤杨 | alder grove 赤杨林 | alder swamp forest 赤杨沼泽林