carbanion ['kɑ:bənaiən]
- carbanion的基本解释
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负碳离子, [化] 阴碳离子
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- carbanions
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At last, in the absence of molecular oxygen, dehydrogenation of FMMH〓 in Photobacterium phosphoreum might be interrupted by the reaction between the Cyanide Alcohol Carbanion and Flavin monoclevtide .
以相加作用的非极性麻醉型有机化合物、极性麻醉型有机化合物和反应性化合物为研究对象,分析了各种相加作用的不同本质。
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On the basis of the Frontier Orbital Theory and three Bonding Principles, the possibility of reaction of active HOSA^- carbanion on polymerization process of MA by alkali catalyst and the mechanism of anionic polymerization of maleic anhydride were studied.
应用前线轨道理论和成键三原则研究了碱催化条件下马来酸酐均聚过程中α-羟基丁二酸酐碳阴离子活性中间体参与反应的可能性及其阴离子聚合机理。
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The results showed that H of HEH and N-Me-HEH was transferred to the α-position of FDCN to form the thermodynamically unfavorable 9- fluorenide carbanion, respectively, while D of the 4, 4-deuterated derivatives of HEH and N-Me-HEH was transferred to the 9-position of FDCN to form 9-fluorenylmalononitrile carbanion.
而模型化合物4—位氘代物上的D则转移到FDCN的9—位,形成了9—芴基丙二腈碳负离子。
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The four most common types are a free-radical, carbanion (carbon-centred negative ion), carbocation (carbon-centred positive ion) or a metal complex (as in Ziegler-Natta polymerisation).
有四种最常见的活性中心类型:自由基、碳负粒子、碳阳离子鎓和金属络合物(在Ziegler-Natta聚合中使用)。
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Such cases as hydride ion transfer from reduced nicotinamide coenzymes or the carbanion generated by base abstraction of a substrate proton may lead to attack at the flavinN-5 positions; some nucleophiles, such as the hydrogen peroxide anion, are added on the C-4a position with its frontier orbital.
从减少烟酰胺辅酶或基片基抽象所产生的质子氢离子负离子转移这种情况可能会导致攻击的flavinN - 5的位置;例如过氧化氢负离子一些亲,被添加在C - 4A条位置其前线轨道
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carbanion:碳负离子
正文 碳负离子(Carbanion)指的是含有一个连有三个基团,并且带有一对孤对电子的碳的活性中间体. 碳负离子带有一个单位负电荷,通常是四面体构型,其中孤对电子占一个 sp3 杂化轨道. 通过比较相应酸的酸性大小,可以大致判断碳负离子的稳定性大小.
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carbanion:碳阴离子
(2) 与PPP途径中非氧化性途径的转醛脢 (transaldolase) 有关;形成胺基酸与PLP结合的中间物(为稳定此Schiff base,常形成碳阴离子 (carbanion)的中间物);胺基酸的消旋作用 (racemization)是催化胺基酸D-form与L-form间的镜像异构作用.
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carbanion:负碳离子
carbanilide 碳酰替 | carbanion 负碳离子 | carbazole 咔唑
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carbanion:负(阴)碳离子
capillary electrophoresis apparatus 毛细管电泳仪 | carbanion 负(阴)碳离子 | carbocation 正(阳)碳离子
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Masked carbanion:掩蔽碳负离子
Carbanion 碳负离子 | Masked carbanion 掩蔽碳负离子 | Carbenoid 卡宾体
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