aromatization [ə'rəumə,tai'zeiʃən]
- aromatization的基本解释
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[化] 芳构化
- 相似词
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Using mordern physical chemistry techniques (such as XRD、 TG-DTA、 IR、 XPS and 〓Xe-NMR)、 chemical adsorption techniques (NH〓-TPD、 H〓-TPD、 TPO、 TPR etc.) and pulse flow microreaction of n-hexane、 methylcyclopentene and n-hexane containing 0.2ppm thiophene, we studied mainly the following three points:(1). the changes occured during the calcination pretreatment of Pt ammine complex supported on β and L zeolites;(2). the effect of structure and acidity-basicity of zeolite on the dispersion and electron state of Pt particles; and (3). the influence of second metal component on the reactivity of nhexane aromatization and sulphur-resistance of Pt/L zeolite catalyst. Several interesting and valuable results are obtained and summerized as follows
本论文运用各种近代物理表征方法(XRD、BET、TG-DTA、IR、XPS和〓Xe-NMR)、化学吸附技术(NH〓-TPD、H〓-TPD、TPO、TPR等)和正己烷、甲基环戊烷及含噻吩正己烷的脉冲微反等方法,着重研究了(1)载Pt的β和L沸石在分解预处理过程中发生的变化;(2)沸石载体结构及酸碱性对Pt粒子分散及电子状态的影响;(3)第二金属组份对载Pt沸石催化剂上正己烷芳构化及抗硫性能的影响等,得到了某些有意义的结果。
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A mechanism involved in the second [5 + 1] annulation step, includinga formal [5 + 1] annulation and accompanied chlorovinylation, chloroformylation,amination and aromatization reactions, is proposed.
并对第二步反应机理进行了推测,其中包括了一个一般的[5 + 1]加成反应及伴随此加成反应而发生的氯化乙烯化,氯化甲酰化,氨化和芳构化反应。
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Generally speaking, the reaction types involvingα-oxoketene--acetals mainly include the regioselective addition-aromatization with organometallic reagents, conjugate addition-cyclization with nitrogen nucleophilicspecies, nucleophilic reactions ofα-carbon, acting as odorless dithiol equivalentsin thioacetalization, Michael additions and [5+1] annulation, as well as the synthetic applications based on the above reactions.
一般来说,基于α-羰基二硫缩烯酮化学的反应主要为:与金属有机试剂的选择性加成反应,与氮亲核体的共轭加成反应,α-碳原子的亲核性及相关反应,烷硫基作为硫醇的替代试剂的应用,α-羰基二硫缩烯酮在碳环、杂环化合物合成中的应用等。
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aromatization:芳香化
外围芳香化(aromatization)雄烯二酮以制造雌激素的能力抑制了性腺的分泌44) 雌激素使下列何种脂肪组成(lipid fractions)减少的效果对于减少(CHD)风险的效果最重要?
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aromatization:香化
周边芳香化(aromatization)雄烯二酮以制造雌激素的能力抑制了性腺的分泌44) 雌激素使下列何种脂肪组成(lipid fractions)减少的效果对於减少(CHD)风险的效果最重要?
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aromatization:芳构化
aromatic plants 芳香植物 | aromatization 芳构化 | aromorphosis 形态演进
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aromatization:芳香(作用);芳构化(作用)
"芳香性;芳香度","aromaticity" | "芳香(作用);芳构化(作用)","aromatization" | "激发","arousal"
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thermoselective aromatization:热选择的芳化
thermoregulator 温度第器 | thermoselective aromatization 热选择的芳化 | thermosetting adhesive 热硬化胶着剂
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