arenes
- arenes的基本解释
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[化] 芳烃
- 更多网络例句与arenes相关的网络例句 [注:此内容来源于网络,仅供参考]
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The B3LYP/6-31G calculations on the four complexes show that the largest interaction energy is-13.98 kJmol^(-1) in the complex composed of HMX and hexaazacalix [3]-p-triarene [3]-2-amido-1, 3, 5-triazine. Results show that intermolecular interaction energies of azacalix [6] arenes with substituted groups are stronger than that without substituted groups, and intermolecular interaction energies of azacalix [6] arenes with amido groups are stronger than that with nitryl groups.
研究发现分子间相互作用能最大的复合物是六氮杂杯[3]-对-三芳烃[3]-2-氨基-1,3,5-三嗪与HMX所形成的复合物,最大相互作用能为-13.98 kJmol^(-1);而且带有取代基的复合物的相互作用能大于没有带取代基的复合物,带有氨基取代基的复合物的相互作用能大于带有硝基取代基的复合物。
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Result showed that tetrasubstituted calix [4] arenes in lower rim were stronger complex abilities than bisubstituted calix [4] arene with transition metal, heavy metal and rare earth ions. But when introducing the aminephenolicalcohols in the 1, 3-bisubstituted calix [4] arenes, the complex abilities were improved.
结果表明:在Lower rim上四取代的杯[4]芳烃配体比1,3-二取代的杯[4]芳烃配体对过渡金属离子,重金属离子及稀土离子有更好的配位能力,但当1,3-二取代的取代基上引入醇胺链型配体时,对金属离子也有很好的配位能力。
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Synthesis of the phenylhydrazone, oxime and semicarbazonederivatives of calix[4]arenesThe reaction of p-formylcalix[4]arenes with phenyl hydrazine,hydroxylamine hydrochloride or semicarbazide hydrochloride afforded thephenylhydrazone, oxime or semicarbazone derivatives of calix[4]arenes,respectively.
酯型杯[4]冠醚的全醚化及性能研究利用氢化钠作为碱,对酯型杯[4]冠醚剩余酚羟基进行烷基化,合成中性杯芳烃酯型冠醚,初步研究了其对金属离子、有机阳离子和中性分子的识别情况,发现其对这些底物缺乏有效作用能力。