ammine complex

ammine complex的基本解释

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[化] 氨合物, 氨络物

与ammine complex相关的网络例句 [注：此内容来源于网络，仅供参考]

In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions（0-D chain）; complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.

合成了8个结构新颖的配合物，并用X-射线单晶结构分析方法确定了晶体结构，分别为： [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构；配合物2借助水分子形成一维链状结构；配合物3、4、5、6是以H4btc为第一配体、phen为第二配体，通过水热法合成的配合物，其中，Co2+、Ni2+、Cu2+为中心离子；配合物3中的二价钴离子具有相同的配位环境，不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境，在配合物4中，一维链通过H4btc上的羧基形成一个二维层结构；配合物5、6是借助H4btc上的羧基形成的一维链状结构；配合物7、8属于异质同晶结构，它们的分子通过分子间氢键形成三维网状结构，H4btc上的羧基失去2个质子，作为一个二价负离子起到电荷平衡作用。

The atomic resolved density of state shows that there is density of Ru on the HOMOs. All the density is localized on the ammine, which reveals that the excited electrons in the Ru complex are delocalized over the ammine ligand.

首先原子分辨的态密度显示HOMO上的密度主要在Ru上，LUMO 上的态密度在ammine上，这说明Ru上激发的电子会转移到ammine配体上。

The first stage was actually the primary purification process, in which most of inorganic ammonium and some total ammine can be removed along with the primary purification process, the second stage was liquid phase oxidation method by sodium hypochlorite, in which inorganic ammonium and total ammine can be further removed.

一段除铵为原有的尾盐一次精制工艺。研究发现，在一次精制的同时，可以除去尾盐中的大部分无机铵及部分总胺，二段除铵采用次氯酸钠液相氧化法，以进一步除去尾盐中无机铵及总胺。

与ammine complex相关的网络解释 [注：此内容来源于网络，仅供参考]

ammine：氨<配位子>

"ammeter","电流计;安培计" | "ammine","氨[配位子]" | "ammine complexes","氨错合物"

ammine complexes：氨错合物

"ammine","氨[配位子]" | "ammine complexes","氨错合物" | "ammon explosive","硝铵炸药"

meta ammine complex：金属 -氨铬合物

met-L-check | 金属染色探裂法 | meta ammine complex | 金属 -氨铬合物 | meta anthracite | 石墨