acridinium
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Four peaks of acridinium of 2 showed pronounced upfield shifts due to the conversion of acridinium to acridane in 5 equiv of either F-(Figure 3b) or AcO-(Figure 3c).
对于与中心吡啶环相邻的质子(ΔHa=1.48ppm)以及相对于吡啶的氮的对位质子((ΔHc=1.47ppm)观察到了最大的化学位移。
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The addition of F-/AcO- to 2 was further confirmed by monitoring the changes in its 1H NMR spectra in the presence of either F- or AcO-(Figure 3). Four peaks of acridinium of 2 showed pronounced upfield shifts due to the conversion of acridinium to acridane in 5 equiv of either F-(Figure 3b) or AcO-(Figure 3c).
F-/AcO-添加到2中通过监测其在存在F-或AcO-时H NMR谱的变化进一步得到确认(图3)。2的吖啶盐的四个峰值证明了由于在5个当量F-(图3b)或AcO-(图3c)中吖啶盐转化成吖啶而引起的明显的高场位移。
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In chapter 2, we introduced the fabrication of two kind of CE-CL interfaces, which are able to be used for the detection of Acridinium ester and its' labeled analytes.
论文的第二部分(包括第2、3、4章)主要涉及毛细管电泳化学发光检测器的研制及应用研究。
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To explore the clinical reliability and usability of the acridinium ester-labeled CLIP and ELISA in detection of AFP to establish a specific, effective, simple and reliable detecting method in our lab.
[目的]探讨吖啶酯标记的化学发光免疫测定(chemiluminescence immunoassay, CLIA)分析技术与酶联免疫吸附试验一步法两种方法检测甲胎蛋白(Alpha-fetoprotein, AFP)的临床可靠性、适用性。建立本室特异、有效、方便、可靠的试验方法。
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The disappearance of the three characteristic absorption peaks corresponding to the acridinium salts and the newly formed peaks at 280 nm for 1 and 288 nm for 2 strongly suggested transformation of the acridinium moiety into the corresponding acridane via anionic addition to the C9 position of the former (Figure 2b).
与吖啶盐相应的三个特性吸收峰的消失以及新形成的峰值(1为280nm,2为288nm),强烈表明了吖啶盐分子部分通过阴离子加入到前者的C9位置而转化成了相应的吖啶(图2b)。
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acridinium oxime:吖啶肟
6.acridine orange 吖啶橙 | 7.acridinium oxime 吖啶肟 | 8.active oxygen 活性氧