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This paper studies the thermal decomposition of a number of dithioesters,trithiocarbonates and xanthates and gives their decomposition rates at various temperature and Arrhenius plots for K_d values.
分析了链转移剂结构对热稳定性的影响，并给出了它们热分解的活化能和指前因子。
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The thermal stabilities of dithioesters, trithiocarbonates and xanthates were also compared,indicating that trithiocarbonates and xanthates are more stabile than dithioesters,while the chain transfer abilities of the latter are usually better than that of the former.So how to balance the chain transfer ability and the thermal stability of RAFT agents is a big challenge.
另外我们比较了双硫酯、三硫酯和磺原酸酯的热稳定性，发现后两者的热稳定性要远远好于前者，但前者的链转移能力一般要大于后两者，所以如何平衡链转移剂的链转移能力和其热稳定性之间的矛盾仍然是个很大的挑战。
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After being oxidated for 34 h, and then the contents of Fe2+ in the 9K liquid solution with 4×10-4mol/ L xanthates, dithiophosphates and D-250 added inreased from 4.03 g/L to 4.64, 4.77 and 5.91g/L, respectively. After leaching for 35 d, the leaching rates of Zn are 92% and 61% respectively. It shows that the flotation reagents (xanthates, D-250) have great effect on the activity of bioleaching bacteria.
研究结果表明：添加4×10-4mol/L的丁基醚醇、乙基黄药、丁胺黑药，氧化34 h后，使 K液体培养基中的Fe2+质量浓度由4.03 g/L分别增加至4.64 g/L， 4.77 g/L和5.91 g/L；浸出35 d后，精矿中的浸出率分别为92%和61%，这进一步验证了浮选药剂对浸矿细菌活性的影响。
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The invention relates to a surface chemistry modified latex which can be obtained by carrying out radical polymerization in emulsion in the presence of at least one ethylenically unsaturated monomer or at least one polymer having ethylinically unsaturated residual bonds, at least one radical polymerization, at least one single, double or triple block polymer which is soluble or dispersible in water, comprising an active group at the end thereof, capable of forming a radical, and chosen from dithioesters, xanthates, thioether-thiones and dithiocarbamates.
本发明涉及具有改良表面化学性质的胶乳，它可以通过在以下物质的存在下进行自由基乳液聚合来获得：至少一种烯属不饱和单体或至少一种含残留烯属不饱和键的聚合物，至少一种自由基聚合引发剂，至少一种水溶性和/或水可分散的单嵌段、二嵌段或三嵌段聚合物，在其端部包括选自二硫酯，硫醚-硫酮，二硫代氨基甲酸酯和黄原酸酯中的能够形成自由基的活性基团。
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XANTHATES：黄原酸盐
TORPEDOES with bursting charge 鱼雷,带有爆炸装药 1.1D | XANTHATES 黄原酸盐 4.2 3342 | XENON 氙 2.2 2036